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While there are some highly polar compounds that reportedly protect the BBB, like the cationic anthocyanidines and their glucosides, most of the compounds are rather lipophilic up to the extreme, e.g., the tetraterpene carotenoids

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[DOI] [Google Scholar] 17.Valenzuela-Cobos J.D., Guevara-Viej F., Grijalva-Endara A., Vicente-Galindo P., Galindo-Villardn P

Pharmacol Res 173:105853 Arbiser JL, Bonner MY, Ward N, Elsey J, Rao S (2018) Selenium unmasks protective iron armor: a possible defense against cutaneous inflammation and cancer

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